Green’s Dictionary of Slang

buff v.2

1. (US gay) to have anal intercourse.

[US]B. Rodgers Queens’ Vernacular 87: anal intercourse [...] buff (fr teen & hustler sl, mid ’50s // buff = polish a surface).

2. to perform oral sex.

[US]T. Williams Crackhouse 120: A master blaster is nothing more than a big rock of crack. But a double master blaster is something altogether different. That’s when a man is being buffed by a girl while he’s smoking on the pipe with crack in it and he comes.
[US]Eble Campus Sl. Oct.

In phrases

buff the button (v.)

of a woman, to masturbate.

[UK]J. Meades Empty Wigs (t/s) 71: I also feared the possibility of Marie-Yvonne buffing up her button.