Green’s Dictionary of Slang

plex v.

1. (US prison) to get psychologically prepared to start a (gang) fight [? SE flex].

[US]Bentley & Corbett Prison Sl. 90: Plex [...] To become bristled and ready to fight.
C-Note ‘Hold It Down Pt. 2’ 🎵 If them boys wanna plex, put a strap to they dome.
[US]T.I. ‘Everything On Me’ 🎵 Now with all due respect, I don’t front, I don’t plex.

2. (US black) to show off.

[US]LL Cool J ‘Do Wop’ 🎵 The girlies want sex, the fellas try to plex.
[US]Ultramagnetic MCs ‘Bust The Facts’ 🎵 Because it’s time to plex more and rhyme fantastic.

3. (US) to show disrespect, to slander [ety. unknown].

[US](con. 1975–6) E. Little Steel Toes 19: Don’t plex on me.

4. (US prison) to be anxious or nervous [? SE perplex].

[US]E. Little Another Day in Paradise 97: Why’s a white boy plexin’ over being called “boy” – it ain’t no thing.
[US]Other Side of the Wall: Prisoner’s Dict. July 🌐 Plexin: To be anxious or nervous. (NY).

In derivatives

plexer (n.)

a trouble-maker.

Z-Ro ‘Mercy’ 🎵 Motherfucking nigga from Texas, steady with the dumb plexers.
Trae ‘Screw Done Already Warned Me’ 🎵 Plexers ain’t never been a problem, I stay strapped for the jealous.