Green’s Dictionary of Slang

b.b. head n.

[the supposed resemblance to b.b. shot, i.e. ‘an air gun pellet having a diameter of approximately 0.45 or 0.56 cm (0.177 or 0.22 inches), used esp. by young people’ (OED)]
(US black)

1. a boy with a tight-curled, ‘knotty’ head.

[US]C. Major Juba to Jive.

2. an unattractive woman, esp. one with short, fuzzy, nappy hair.

[US]E. Folb Runnin’ Down Some Lines 228: B.B. head 1. Unattractive female. 2. Unkempt female. 3. Female with short, nappy hair.