Green’s Dictionary of Slang

brimstone buster n.

also brimstone peddler
[SE brimstone, hellfire + buster, a breaker or smasher]

(US) a ranting preacher.

FWP Guide MT 99: This followed a period of preaching in saloons, dance halls, and gambling houses, where roulette wheels, cards tables, and other paraphernalia were pushed aside to let the ‘brimstone busters’ hold forth [DARE].
[US](con. 1820s) W.E. Wilson Wabash 224: An imitation of the new brimstone peddler at the Old Pigeon Hard-Shell Baptist Church.