Green’s Dictionary of Slang

kissyface n.

1. (orig. US teen/campus) the act of kissing (in cite 2008, as opposed to intercourse).

Scott Sullivan Shortest, Gladdest Years (1963) 153: Oh, I admit to bit of kissyface now and then.
[US]G. Underwood ‘Razorback Sl.’ in AS L:1/2 62: Let’s have a little kissyface.
[US]G.V. Higgins Rat on Fire (1982) 80: Billy hugged her and gave her kissy-face.
[US]D.R. Pollock ‘Honolulu’ in Knockemstiff 188: ‘Look, babe, we ain’t here for no kissy-face. Just bend over and say your prayers’.
[[Aus] J.J. DeCeglie ‘Death Cannot Be Delegated’ in Crime Factory: Hard Labour [ebook] Looking at herself in that bigarse mirror [...] Making kissy faces to her double].

2. used fig. to describe any intimate meeting, conversation etc.

[US]Wall Street Journal letters 6 Mar. A13/1–2: Remember Mike Wallace’s kissy-face meeting with the Ayatollah years ago, There’s Mr. Wallace, kneeling on a pillow, head to the side, gazing up as Khomeini seriously intoned some sort of nonsense. Mr. Rather must have been moved by that scene, because his visit closely paralleled Mr. Wallace’s.

In phrases

play kissyface (v.) (also kissy-kissy, play kissy-ass, ...kissy-poo)

1. (US) to kiss and cuddle.

in J. Davies College Vocab.
[US]R. Campbell Alice in La-La Land (1999) 163: Playing kissy face with him the way she was doing was a game for someone considerably younger.
[US]J. Wambaugh Golden Orange (1991) 221: Tess’s playing kissy face with a guy that wears sneakers a Shanghai longshoreman wouldn’t be caught dead in.
[US](con. 1975–6) E. Little Steel Toes 111: I [...] watch these two play kissyface for a second.

2. in fig. use, to befriend, often insincerely.

[UK]Guardian G2 25 Mar. 4: I don’t need to play kissy-ass.