Green’s Dictionary of Slang

big spit n.

also long spit

(Aus.) the act of vomiting; also as v.

R.A.N. News (Sydney) 20 Mar. 4: Down in the Strait / The waves rolled high / The waves rolled wide / And the ‘Big Spit’ starters lined the side [AND].
[Aus]F.J. Hardy in Great Aus. Lover Stories 63: Euphemisms for vomit [...] include spue, burp, hurl, the big spit, the long spit.
[Aus]R. Aven-Bray Ridgey-Didge Oz Jack Lang 21: Big Spit Vomit.
[NZ]McGill Dict. of Kiwi Sl. 14/2: big spit, the vomit.
[NZ]McGill Reed Dict. of N.Z. Sl. [as cit. 1988].
[Aus]J. Miller Lingo Dict. 16: big spit; to vomit.

In phrases

go (for) the big spit (v.)

(Aus.) to vomit.

[Aus]B. Humphries Barry McKenzie [comic strip] in Complete Barry McKenzie (1988) 67: You can keep the cider, thanks [...] It always makes me go the big spit.
I. Fleming You Only Live Twice 46: Soon as we got home from that lousy cat house, I had to go for the big spit.
[Aus]A. Buzo Rooted I iii: Remember the time he got sick at Davo’s twenty-first and went for the big spit? He said to me ‘Jees I feel crook’, and then he [...] shoved his head out the window and burped a rainbow.
[Aus]B. Humphries Traveller’s Tool 119: This is a reference to witchetty grubs which, like all ethnic delicacies, would more than likely have you and me going for the big spit and yodelling into the white telephone.
[NZ]McGill Dict. of Kiwi Sl. 14/2: big spit, the vomit, often in phr. ‘to go for the big spit’.
[NZ]McGill Reed Dict. of N.Z. Sl. [as cit. 1988].