Green’s Dictionary of Slang

postilion v.

[SE postilion, a swift messenger; thus the practice makes one ‘come v.1 faster’]

to insert and manipulate a finger in the anus of a sexual partner as a means of increasing sexual excitement.

Power of Mesmerism [ebook] My left hand passed round his loins, caressing his fine prick and balls as it worked in and out of her beautiful brown bumhole, whilst my right forefinger postilioned him behind.
[UK] Tableaux Vivants (translation) xi 95: The fair houri was postillioning me [OED].
[UK]Farmer & Henley Sl. and Its Analogues.
G. Legman Oragenitalism i 90: Postillioning can best be done by the middle finger.