Green’s Dictionary of Slang

baby paps n.

also baby’s paps
[rhy. sl.; ? resemblance of a cap to the breast]

caps.

[UK]‘Ducange Anglicus’ Vulgar Tongue.
[UK]Hotten Dict. of Modern Sl. etc.
[US]Matsell Vocabulum.
[UK]Sl. Dict.
[UK]J. Franklyn Dict. of Rhy. Sl. 35/1: baby’s pap Cap, from c. 1855 [...] The term went into decline when caps ceased to be the exclusive fashion for workmen and charwomen – c. 1918.