Green’s Dictionary of Slang

catch ’em alive oh! excl.

a popular, if meaningless, catchphrase.

[UK]Dickens ‘Slang’ in Household Words 24 Sept. 74/2: Let some fellow rush forward and roar out ‘It’s all serene,’ or ‘Catch ’em alive, oh!’ (this last is sure to take) pit, boxes, and gallery roar with laughter.
[UK]Sherborne Mercury 5 Jan. 3/7: The Catch’em Alive Oh! Joint-Stock Bank [...] Directors Lord Dundreary M.P., A.S.S., Lord Tomnoddy, M.P., A.S.S.