Green’s Dictionary of Slang

purple n.

[the colour of the pills]
(drugs)

1. amphetamine.

[UK]P. Carstairs Concrete Kimono 227: He was [...] one minute ebullient, the next murderously low, and it made me wonder if he took snow or maybe purples.

2. LSD.

[US]R.R. Lingeman Drugs from A to Z (1970).
[US]E.E. Landy Underground Dict. (1972).

3. ketamine.

[US]ONDCP Street Terms 17: Purple — Ketamine.

4. (N.Z. prison) a 30 mg morphine sulphate tablet.

[NZ]D. Looser Boobslang [U. Canterbury D.Phil. thesis] 148/2: purple n. 1 a 30mg morphine sulphate tablet .

5. (N.Z. prison) a halcion tablet.

[NZ]D. Looser Boobslang [U. Canterbury D.Phil. thesis] 148/2: purple n. 2 a halcyon pill. [the next strongest after a blue].

In phrases

purple someone down (v.) [the purple colour of the Xanax tranquillizer]

(US drugs) to calm someone down, thanks to tranquillizers.

[US]S. Morgan Homeboy 268: Boy, was Sunny glad Cherry purpled her down.