Green’s Dictionary of Slang

peach n.2

[peach v. (1)]

a detective, esp. as employed by a stage-coach or omnibus company to check receipts.

[UK]Hotten Sl. Dict. 197: peach an informer against omnibus conductors and drivers, one especially hired by the proprietors to count passengers and stoppages. The term is in frequent use amongst omnibus-men.