Green’s Dictionary of Slang

Zambuck n.

also Zambuk
[name of Zam-buk, a proprietary antiseptic ointment; Zambuk website: ‘The word Zam-Buk originated in New Zealand, and was used to describe someone who administered first aid to wounded sportsmen. A “Zambuck” was a member of the Order of St. John, which was established at the time of the Crusades to care for the injured’]

(Aus.) a St John’s Ambulance man.

[Aus]Biz (Fairfield, NSW) 7 June 8/2: One of the most useful, though unassuming officials at district football matches is the ‘Zambuck Man,’ as he is familiarly known.
[Aus]Baker Popular Dict. Aus. Sl. (2nd edn).
[Aus]R. Raven-Hart Canoe in Aus. 145: Ambulance men, ‘Zambuks’ in Australian slang, are often busy.
[NZ]G. Slatter Gun in My Hand 80: The ambulance men run for the prone body on the field. The game is in a serious state because there is not the usual fatuous cry of zambuck from some oaf in the crowd who has never known the shock and pain of a footbal injury.
[NZ]G. Slatter Pagan Game (1969) 172: Call on the zambucks to cart him off.
[Aus]Bulletin 6 Mar. 43: If you don’t know what a Zambuck is, it’s someone in the black and white uniform of the St John Ambulance Brigade doing honorary duty at a sports arena, ready to dash on the field with everything from liniment to stretcher.
[NZ]McGill Dict. of Kiwi Sl. 128/2: zambuck St John ambulance officer; from black and white uniform likened to the black and white container of Zambuck ointment.
[Aus]R.G. Barrett Mud Crab Boogie (2013) [ebook] But after [...] the zambuck hit him with the smelling salts he was in there again.
(ref. to 1962) R. Sprigg at www.simpsondesert.fl.net.au 🌐 There were plenty of anxious moments for me though as a zambuck responsible for the well-being of more than forty five workmen and me with only a St Johns Ambulance First Aid Certificate and an RFDS chest to back me up on the ground.